Contact with metals may evolve flammable hydrogen gas. Protect containers from physical damage. Be familiar with materials Dry Ice is incompatible with. For example, aldehydes are both flammable and toxic. Tetrazoles include, 2-methyl, 2-ethyl, 5-ethyl, 2-methyl-5-vinyl, 5-amino-2-ethyl [US Pat. Protect containers from physical damage. Phosphine can explode with powerful oxidizers. The absorption and excretion of (14)C-benzoyl chloride was studied in male and female Holtzman albino rats. Examples of Incompatible Chemicals. Keep container closed when not in use. These flammable or explosive gases can form when CO2 extinguishers are used to fight hydride fires. Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.Reaction with water or moist air may release toxic, corrosive or flammable gases. Phosphine is a colorless, flammable, and explosive gas at ambient temperature that has the odor of garlic or decaying fish. GHS Hazard Statements: H225: Highly Flammable liquid and vapor [Danger Flammable liquids]H302: Harmful if swallowed [Warning Acute toxicity, oral]H312: Harmful in contact with skin [Warning Acute toxicity, dermal]H315: Causes skin irritation [Warning Skin corrosion/irritation]H319: Causes serious eye irritation [Warning Serious eye damage/eye 12 C) which is irritating and toxic in the gaseous state. Oxidizers (Yellow letters on black background). Esters react with acids to liberate heat along with alcohols and acids. Store away from oxidizers and other incompatible materials. Types of reagents are precipitants, solvents, oxidizers, reducers, fluxes, and colorimetric reagents. An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent (called the reductant, reducer, or electron donor).In other words, an oxidizer is any substance that oxidizes another substance. storage of flammable liquids. For electric isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. It is incompatible with other storage groups and should be stored seperately. Caution, flammable vapors may accumulate in closed containers. Avoid inhalation. Oxidizers, reducing agents, and fuels should be stored separately to prevent contact in the event of an accident. Secure it to prevent unauthorized access. Use of water spray when fighting fire may be inefficient. For electric vehicles or equipment, ERG (150 feet) for liquids and at least 25 meters (75 feet) for solids. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Ground and bond the drum and receiving vessel when transferring flammable liquids from a drum to prevent static charge buildup. Flammable gases. to confirm spill areas. Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: CAUTION: The majority of these products have a very low flash point. Use approved equipment, including labelled safety containers, for flammable and combustible liquids. TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. CAUTION: Hydrogen (), Deuterium (), Hydrogen, refrigerated liquid and Hydrogen and Methane mixture, compressed will burn with an invisible flame.Use an alternate method of detection (thermal camera, broom corrosive or flammable Keep away from strong acids. Picric acid can form explosive salts with many metals, or by itself when dry. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. But, flammability trumps toxicity. An investigation revealed that the storage tank did not contain any residual contamination from previous products and the 1,1,1-trichloroethane was not contaminated with highly flammable liquids. Emergency Measures. Pyrophoric liquids, solids and gases, nondetonable. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). During the purging of the pipeline, a volume of nitrogen equivalent to approximately 1/2 tank volume had been injected near the base of the tank. [Flammable Liquids (Water-Immiscible)]: Some are TIH materials themselves, e.g., chlorine, borides, and phosphides to generate toxic or flammable gases. Inventories must include the full chemical name, location of storage, and associated hazard (e.g. Organic peroxides, Class I. Oxidizers, Class 3, that are used or stored in normally open containers or systems, or in closed containers or systems pressurized at more than 15 pounds per square inch gauge (103 kPa). Forms explosive complexes with ether, dimethylamine and various tetrazoles. It is incompatible with fuels and nitro compounds. Oxidizers and flammable gases should be kept at least 20 ft. away from combustible materials and/or incompatible gases or substances. Interaction with water is violent and may be explosive, even with ice [Sidgwick, 1950, p. 1156]. CHLORINE TRIFLUORIDE is a low-boiling liquid (b.p. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). A highly reactive oxidant, it is spontaneously flammable and used as a rocket propellant. Flammable liquids - * Flammable solids - * Self-reactive substances and mixtures - * Pyrophoric liquids - * Incompatible materials: Oxidizing agents, amines, strong bases. An inventory of all chemicals must be maintained. Store in a cool, dry, well-ventilated area away from incompatible substances. Combustible liquids have a flashpoint above 100 F. Never store incompatible liquids near one another. Store, handle and use flammable and combustible liquids in well-ventilated areas. Store aldehydes in a flammable storage cabinet. During work: Perform all operations in a well-ventilated area. It contains some of the more common incompatible materials. reclamation or disposal. Keep away from reducing agents. Of the organic wastes produced, 100% are recycled through Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Store separately outdoors in flammable storage cabinets. For electric isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Spills Use approved containers for disposal of rags and other work. No information available. Diesel Fuel January 23, 2015 Page 4 of 7 SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION While it is always best to segregate, acetic acid can be stored other flammable liquids. storage of flammable liquids. Protect containers from physical damage. Store away from oxidizers and other incompatible materials. This can lead to frostbite. Keep away from flammable liquids. 7.2.4 Oxidizers 7.2.5 Poisons 7.2.6 Explosives or unstable reactives, such as picric acid. The gas is heavier than air and may travel along the ground to an ignition source. Evaluate the direction of product travel, diking, sewers, etc. Contact with metals may evolve flammable hydrogen gas. storage of flammable liquids. Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Avoid storage on wood floors. Reaction with water may generate much heat that will increase SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION Exposure Guidelines: INGREDIENTS EXPOSURE LIMITS Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]: DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Flammable liquids, oxidizers, poisons, and acids: Flammable Liquids: Store in flammable storage cabinet and away from sources of ignition. H225: Highly Flammable liquid and vapor [Danger Flammable liquids] H304: May be fatal if swallowed and enters airways [Danger Aspiration hazard] H315: Causes skin irritation [Warning Skin corrosion/irritation] H336: May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects] Belongs to the Following Reactive Group(s) Hydrocarbons, Aliphatic Saturated; Potentially Incompatible Absorbents. Sodium fluoride is an inorganic chemical compound that is a source of the fluoride ion in many applications, including dental care and radiographic imaging when it is used as [Fluoride ion F-18].Sodium fluoride's benefits on dental health were first observed in the 1930s, when individuals in communities with fluoridated drinking water showed less tooth decay than those without Containers may explode when heated. Store flammable and combustible liquids away from incompatible materials (e.g., oxidizers). The graphic above shows that flammable liquids have a flashpoint below 100 F (37.8 C). Specific Waste Management Requirements 5.2 Chemical Waste Management 5.2.1 Definition 5.2.2 Packaging 5.2.3 Labelling 5.2.4 Storage 5.2.5 Special Cases 5.2.6 Collection Schedule Chemical wastes are not treated on campus; the majority are recycled. Always store flammable materials in a flammable storage cabinet, even if the chemical has other hazards. Containers may explode when heated. Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. 3 396 170, 1968]. When flammable liquids are stored with other materials, care needs to be taken to separate them from any incompatible materials by a distance of at least 20 feet or by a partition. Oxidizers (e.g., nitrates, perchlorates, bromates, permanganates, peroxides, iodates) Organic Peroxides (e.g., benzoyl peroxide, cumene hydroperoxide, methyl ethyl ketone peroxide) Corrosivity. Store away from oxidizers and other incompatible materials. Contact with metals may evolve flammable hydrogen gas. Contact with metals may evolve flammable hydrogen gas. Consider wind direction; stay upwind and uphill, if possible. This also means storing certain chemical groups away from other chemical groups like oxidizers and flammables. Following single oral doses of 9 to 13 mg/kg, benzoyl chloride was rapidly absorbed from the gastrointestinal tract and efficiently eliminated in An explosion resulted [MCA Case History 128(1962)] Incompatible with strong oxidizers. Ingredients shall not be stored with incompatible materials. SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION Exposure Guidelines: INGREDIENTS EXPOSURE LIMITS Incompatible with many materials including strong oxidizers, metals, strong nitric acid, bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, Use appropriate personal protective equipment (PPE): Wear closed-toed shoes that cover the feet. Avoid skin contact with Dry Ice. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Use only the quantity needed at the time. Cryogenic fluids, flammable. Response Recommendations. Laboratory Hazardous Waste Management and Disposal Manual 5. Containers may explode when heated. When heated to decomposition, it emits highly toxic fumes of oxides of sulfur. 1910.109(h)(3)(iii)(e) Peroxides and chlorates shall not be used. The following list is not a complete listing of incompatible materials. Evacuate nonessential personnel and remove or secure all ignition sources. Flammable liquids also need to be stored at least 25 from oxidizers and Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. The oxidation state, which describes the degree of Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. Containers may explode when heated. For electric vehicles or equipment, ERG (150 feet) for liquids and at least 25 meters (75 feet) for solids. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
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